Person:
Cabrera González, Justo Enrique

Profile Picture
First Name
Justo Enrique
Last Name
Cabrera González
URI
https://hdl.handle.net/20.500.14352/84486
Affiliation
Universidad Complutense de Madrid
Faculty / Institute
Ciencias Químicas
Department
Química Orgánica
Area
Identifiers
UCM identifierORCIDScopus Author IDWeb of Science ResearcherIDDialnet ID

Filters

20191
Reset filters

Settings

Author: Núñez, Rosario × Has files: false ×

Search Results

Now showing 1 - 1 of 1
  • Thumbnail Image
    Item
    Synthesis and self-assembly of a carboranecontaining ABC triblock terpolymer: morphology control on a dual-stimuli responsive system
    (Polymer Chemistry, 2019) Fernáncez Alvarez, Roberto; Hlavatovicová, Eva; Rodzén, Krzysztof; Strachota, Adam; Kereïche, Sami; Matejicek, Pavel; Cabrera González, Justo Enrique; Núñez, Rosario; Uchman, Mariusz
    Amphiphilic triblock terpolymers have attractive applications in the preparation of nanoparticles with controlled morphology. An additional level of morphology control can be provided by reactive blocks, whose interactions with the solvent vary under different stimuli. In this work, we synthesized a triblock terpolymer (poly(acrylic acid)-b-poly(4-hydroxystyrene)-b-poly{1-[4-(1-methyl-1,2-dicarba-closo-dodecaborane-2-yl methyl)-phenyl]ethylene}) (PAA-b-PHS-b-PSC) containing carboranes as pendant groups by reversible addition fragmentation chain transfer (RAFT) polymerization and subsequently studied its behavior in aqueous solution. Once the nanoparticles were formed, the solubility of the second and third blocks was changed via pH and CsF reactions, respectively. The resulting micelles work as an ON/OFF system, using changes in fluorescence intensity at different pH values.