RT Journal Article
T1 Controlling Vilsmeier-Haack processes in meso-methylBODIPYs: A new way to modulate finely photophysical properties in boron dipyrromethenes
A1 Palao Utiel, Eduardo
A1 Montalvillo Jiménez, Laura
A1 Esnal Martínez, Ixone
A1 Prieto Montero, Ruth
A1 Rodríguez Agarrabeitia, Antonia R
A1 García Moreno, Inmaculada
A1 Bañuelos Prieto, Jorge
A1 López Arbeloa, Íñigo María
A1 Moya Cerero, Santiago de la
A1 Ortíz García, María Josefa
AB In the herein work we report the fine and selective control of competitive processes when submitting meso-methylBODIPYs to Vilsmeier-Haack reaction conditions. These competitive processes generate BODIPYs with opposed photophysical properties, from highly fluorescent dyes enabling laser emission, to non-fluorescent singlet-oxygen photosensitizers. The synthetic control is exerted on the basis of the structure of the starting BODIPY, as well as the electrophilic character (hard or soft) of the formylating reagent.
PB Elsevier
SN 0143-7208
YR 2017
FD 2017-06
LK https://hdl.handle.net/20.500.14352/18156
UL https://hdl.handle.net/20.500.14352/18156
LA eng
NO Received 10 November 2016, Revised 16 January 2017, Accepted 16 February 2017, Available online 20 February 2017.
NO Ministerio de Economía y Competitividad (MINECO)
NO Gobierno Vasco
DS Docta Complutense
RD 6 may 2024