RT Journal Article
T1 A straightforward electroactive π‐extended tetrathiafulvalene (exTTF) building block
A1 Molina Ontoria, Agustín
A1 García Cervilla, Raúl
A1 Gouloumis, Andreas
A1 Giacalone, Francesco
A1 Torres, M. Rosario
A1 Martín León, Nazario
AB The synthesis and X-ray structure of a new and readily available exTTF derivative (6) bearing a methyltriphenylphosphonium bromide moiety as a new building block for the construction of electroactive molecules is reported. The phosphonium salt 6, which was prepared in one step from 2-hydroxymethyl-exTTF as a stable yellow solid in 84 % yield, efficiently undergoes Wittig olefination reactions with a variety of aldehydes to predominantly form the E isomer. Electronic spectra and cyclic voltammetry of the novel compounds reveal the electronic communication between the electroactive units.
PB WILEY-VCH
SN 1434-193X
SN 1099-0690
YR 2012
FD 2012-05-22
LK https://hdl.handle.net/20.500.14352/115076
UL https://hdl.handle.net/20.500.14352/115076
LA eng
NO Ministerio de Economía y Competitividad
NO Comunidad de Madrid
DS Docta Complutense
RD 8 abr 2025