RT Journal Article
T1 Effect of Incarcerated HF on the Exohedral Chemical Reactivity of HF@C60
A1 Vidal, Sara
A1 Izquierdo, Marta
A1 Alom, Shamim
A1 García-Borrás, Marc
A1 Filippone, Salvatore
A1 Osuna, Silvia
A1 Solà, Miquel
A1 Whitby, Richard J.
A1 Martin León, Nazario
AB The first chemical modification on the brand new endohedral HF@C60 is reported. In particular, the isomerization from optically pure (2S,5S)-cis-pyrrolidino[3,4:1,2][60]fullerene 2b to (2S,5R)-trans-pyrrolidino[3,4:1,2][60]fullerene 2b has been studied and compared with empty C60 (2a) and endohedral H2O@C60 (3). The comparative study shows a kinetic order for the isomerization process of H2O@C60 ˃ HF@C60 ˃ C60, thus confirming the effect of the incarcerated species on the zwitterionic intermediate stability.
PB RSC
SN 1359-7345
YR 2017
FD 2017-10-14
LK https://hdl.handle.net/20.500.14352/18364
UL https://hdl.handle.net/20.500.14352/18364
LA eng
NO Unión Europea. FP7
NO Unión Europea. H2020
NO Ministerio de Economía y Competitividad (MINECO)
NO Comunidad de Madrid
NO Catalan DIUE
NO FEDER
NO Engineering and Physical Sciences Research Council
NO Ramon Areces Foundation and S. O. the European Commission for CIG project
DS Docta Complutense
RD 29 abr 2024