RT Journal Article
T1 Transition-metal-free three-component synthesis of tertiary aryl amines from nitro compounds, boronic acids, and trialkyl phosphites
T2 Síntesis de tres componentes sin metales de transición de arilaminas terciarias a partir de compuestos nitro, ácidos borónicos y fosfitos de trialquilo
A1 García Csaky, Aurelio
A1 Roscales García, Silvia
AB The synthesis of aromatic amines is a hot topic of continuous interest in chemistry. An exceptionally versatile three-component reaction that directly transforms inexpensive nitro compounds, boronic acids, and trialkyl phosphites into tertiary aromatic amines has been realized. The reaction tolerates alkyl and aryl substituents on the nitro and boronic acid moieties, as well as functionalized phosphites. No transition-metal catalysis is required. The method is orthogonal to other classical metal-catalyzed syntheses since it tolerates the presence of halogens, and also permits the synthesis of functionalized compounds such as alpha-amino ester derivatives.
PB Wiley
SN 1615-4169
YR 2019
FD 2019-10
LK https://hdl.handle.net/20.500.14352/113465
UL https://hdl.handle.net/20.500.14352/113465
LA eng
NO Adv. Synth. Catal. 2020, 362, 111
NO Ministerio de Ciencia, Innovación y Universidades
DS Docta Complutense
RD 4 abr 2025