RT Journal Article
T1 How oxidation state and lattice distortion influence the oxygen evolution activity in acid of iridium double perovskites
A1 Retuerto, Maria
A1 Pascual, Laura
A1 Pique, Oriol
A1 Kayser González, Paula
A1 Abdel Salam, Mohamed
A1 Mokhtar, Mohamed
A1 Alonso, Jose Antonio
A1 Peña, Miguel
A1 Calle-Vallejo, Federico
A1 Rojas, Sergio
AB In view of iridium's scarceness and high cost, Ir-containing catalysts for water electrolyzers should have low loadings and maximal utilization. Here, we studied low-Ir-content, highly active, double perovskites (Sr2MIrO6, M = Ni, Co, Sc and Fe) for the oxygen evolution reaction (OER) in acid combining electrochemical experiments, DFT, and advanced characterization techniques. The initial OER performance depends on Ir's oxidation state and the geometric features of IrO6 frameworks, which are tuned by the choice of M. Higher oxidation states, particularly Ir6+, enhance the OER activity: Sr2NiIrO6 and Sr2CoIrO6 display potentials of ∼1.53 V at 10 mA cm−2, comparable to the best Ir-based catalysts in the literature. However, because of their less symmetric structures, perovskites with Ir6+ are less stable, prone to surface reconstruction and their cations leach under OER conditions. These results show that improved iridium-based OER electrocatalysts in acid can be designed by balancing their activity and stability.
PB Royal Society of Chemistry
SN 2050-7488
YR 2021
FD 2021
LK https://hdl.handle.net/20.500.14352/92542
UL https://hdl.handle.net/20.500.14352/92542
LA eng
NO Retuerto, María, et al. «How Oxidation State and Lattice Distortion Influence the Oxygen Evolution Activity in Acid of Iridium Double Perovskites». Journal of Materials Chemistry A, vol. 9, n.o 5, 2021, pp. 2980-90. https://doi.org/10.1039/D0TA10316K.
NO Ministerio de Economía y Competitividad (España)
NO Ministerio de Ciencia, Investigación y Universidades (España)
NO Generalitat de Catalunya
DS Docta Complutense
RD 7 abr 2025