RT Journal Article
T1 Trapping Ag(I) ions by a Pd8 metallacrown molecule to form an unusual nonanuclear AgPd8 cation
A1 Calleja, Fernando
A1 Cortijo Montes, Miguel
A1 Perles Hernáez, Josefina
A1 Herrero Domínguez, Santiago
A1 Jiménez Aparicio, Reyes
AB The {[Pd(µ-SC6F5)(µ-dppm)Pd](µ-SC6F5)}4 (dppm = methanediylbis(diphenylphosphane)) (Pd8) metallacrown traps Ag(I) cations giving {Ag[Pd(µ3-SC6F5)(µ-dppm)Pd]4(µ-SC6F5)4}(X) (X = SO3CF3− (AgPd8a), SbF6− (AgPd8b) and ClO4− (AgPd8c)) and {Ag[Pd(µ3-SC6F5)(µ-dppm)Pd]4(µ-SC6F5)4}2[Pt(C6F5)4] (AgPd8d). The insertion of silver increases significantly the stability of the cluster that is stable in solution even in the presence of light, because of the macrocyclic effect.
PB Elsevier
SN 0020-1693
YR 2019
FD 2019
LK https://hdl.handle.net/20.500.14352/93142
UL https://hdl.handle.net/20.500.14352/93142
LA eng
NO Calleja, Fernando B., et al. «Trapping Ag(I) Ions by a Pd8 Metallacrown Molecule to Form an Unusual Nonanuclear AgPd8 Cation». Inorganica Chimica Acta, vol. 488, marzo de 2019, pp. 56-61.  https://doi.org/10.1016/j.ica.2018.12.049.
NO Ministerio de Economía y ́Competitividad (España)
NO Comunidad de Madrid
DS Docta Complutense
RD 22 abr 2025