RT Journal Article
T1 Robust large area molecular junctions of selfassembled monolayers of a model helical paddlewheel complex
A1 Coloma Manjón-Cabeza, Isabel
A1 Buffeteau, Thierry
A1 Pecastaings, Gilles
A1 Herrero Domínguez, Santiago
A1 Hillard, Elizabeth
A1 Rosa, Patrick
A1 Cortijo Montes, Miguel
A1 Gonidec, Mathieu
AB We report the preparation of a helical complex and its study in molecular junctions. We show that the SAMs of this racemic compound present an electrically robust behaviour which will pave the way for future studies of the CISS effect with analogous enantiopure compounds.
PB Royal Society of Chemistry
SN 2040-3364
YR 2025
FD 2025
LK https://hdl.handle.net/20.500.14352/119232
UL https://hdl.handle.net/20.500.14352/119232
LA eng
NO Coloma, I.; Buffeteau, T.; Pecastaings, G.; Herrero, S.; Hillard, E.; Rosa, P.; Cortijo, M.; Gonidec, M. Robust Large Area Molecular Junctions of Self-Assembled Monolayers of a Model Helical Paddlewheel Complex. Nanoscale 2025, 10.1039.D5NR00050E. https://doi.org/10.1039/D5NR00050E.
NO The author acknowledge support from the Universidad Complutense de Madrid (GRFN32/23, GRFN24/24 and project PR3/23-30828), the France 2030 government investment plan managed by the French National Research Agency under grant reference PEPR SPIN – SPINMAT ANR-22-EXSP-0007, the Imperial College – CNRS joint PhD program, Quantum Matter Bordeaux, the MaelStroM project (CNRS MITI program), the National Research Agency project AnaCrU-CISS (ANR-23-CE09-0026) and the GPR Light project LIGHT-057-ChiroSurf. I.C. acknowledges predoctoral grant from the Complutense University of Madrid and Banco Santander (CT82/20-CT83/20). The authors warmly thank J.P. Salvetat of the Placamat service unit (France) for the ToF-SIMS measurements and Stéphane Toulin for assistance with the open data repository. Computer time for the theoretical calculation was provided by the computing facilities MCIA (Mésocentre de Calcul IntensifAquitain) of the Université de Bordeaux.
NO Universidad Complutense de Madrid
NO Agence Nationale de la Recherche (France)
NO Imperial College
NO Banco Santander
NO Université de Bordeaux
DS Docta Complutense
RD 9 sept 2025