RT Journal Article T1 Production of Oligosaccharides from Agrofood Wastes A1 Cano, María Emilia A1 García Martín, Alberto A1 Comendador Morales, Pablo A1 Wojtusik, Mateusz A1 Santos Mazorra, Victoria Eugenia A1 Kovensky, José A1 Ladero Galán, Miguel AB The development of biorefinery processes to platform chemicals for most lignocellulosic substrates, results in side processes to intermediates such as oligosaccharides. Agrofood wastes are most amenable to produce such intermediates, in particular, cellooligo-saccharides (COS), pectooligosaccharides (POS), xylooligosaccharides (XOS) and other less abundant oligomers containing mannose, arabinose, galactose and several sugar acids. These compounds show a remarkable bioactivity as prebiotics, elicitors in plants, food complements, healthy coadyuvants in certain therapies and more. They are medium to high added-value compounds with an increasing impact in the pharmaceutical, nutraceutical, cosmetic and food industries. This review is focused on the main production processes: autohydrolysis, acid and basic catalysis and enzymatic saccharification. Autohydrolysis of food residues at 160–190 °C leads to oligomer yields in the 0.06–0.3 g/g dry solid range, while acid hydrolysis of pectin (80–120 °C) or cellulose (45–180 °C) yields up to 0.7 g/g dry polymer. Enzymatic hydrolysis at 40–50 °C of pure polysaccharides results in 0.06–0.35 g/g dry solid (DS), with values in the range 0.08–0.2 g/g DS for original food residues. PB MDPI SN 2311-5637 YR 2020 FD 2020-03-08 LK https://hdl.handle.net/20.500.14352/8249 UL https://hdl.handle.net/20.500.14352/8249 LA eng NO Ministerio de Economía y Competitividad (MINECO) NO Agence Nationale de la Recherche DS Docta Complutense RD 3 abr 2025