%0 Journal Article %A Sánchez Blázquez, Patricia %T The X-shooter Spectral Library (XSL): Data Release 3 %D 2022 %@ 0004-6361 %U https://hdl.handle.net/20.500.14352/72107 %X We present the third data release (DR3) of the X-shooter Spectral Library (XSL). This moderate-to-high resolution, near-ultraviolet-to-near-infrared (350-2480 nm, R similar to 10 000) spectral library is composed of 830 stellar spectra of 683 stars. DR3 improves upon the previous data release by providing the combined de-reddened spectra of the three X-shooter segments over the full 350-2480 nm wavelength range. It also includes additional 20 M-dwarf spectra from the ESO archive. We provide detailed comparisons between this library and Gaia EDR3, MILES, NGSL, CaT library, and (E-)IRTF. The normalised rms deviation is better than D = 0.05 or 5% for the majority of spectra in common between MILES (144 spectra of 180), NGSL (112/116), and (E-)IRTF (55/77) libraries. Comparing synthetic colours of those spectra reveals only negligible offsets and small rms scatter, such as the median offset(rms) 0.001 +/- 0.040 mag in the (box1 - box2) colour of the UVB arm, -0.004 +/- 0.028 mag in (box3 - box4) of the VIS arm, and -0.001 +/- 0.045 mag in (box2 - box3) colour between the UVB and VIS arms, when comparing stars in common with MILES. We also find an excellent agreement between the Gaia published (BP - RP) colours and those measured from the XSL DR3 spectra, with a zero median offset and an rms scatter of 0.037 mag for 449 non-variable stars. The unmatched characteristics of this library, which combine a relatively high resolution, a large number of stars, and an extended wavelength coverage, will help us to bridge the gap between the optical and the near-IR studies of intermediate and old stellar populations, and to probe low-mass stellar systems. %~