TY - JOUR AU - Díaz Guillén, M. R. AU - Moreno, K. J. AU - Díaz Guillén, J. A. AU - Fuentes, A .F. AU - Naval, K. L. Ngai AU - Garcia Barriocanal, Javier AU - Santamaría Sánchez-Barriga, Jacobo AU - León Yebra, Carlos PY - 2008 DO - 10.1103/PhysRevB.78.104304 SN - 1098-0121 UR - https://hdl.handle.net/20.500.14352/51401 T2 - Physical review B AB - In this work we evaluate the effect of cation size on the dc activation energy needed for oxygen ion migration, E_(dc), in highly disordered pyrochlore-type ionic conductors A_(2)B_(2)O_(7). Twenty six compositions with the general formula,... LA - eng PB - American Physical Society KW - Electrical relaxation KW - Constituent oxides KW - Coupling model KW - Spin ice KW - Conductivity KW - Migration KW - Diffusion KW - Gd_(2)Ti_(2)O_(7) KW - Glasses KW - Melts. TI - Cation size effects in oxygen ion dynamics of highly disordered pyrochlore-type ionic conductors TY - journal article VL - 78 ER -