RT Journal Article
T1 Acidic triggering of reversible electrochemical activity in a pyrenetetraone-based 2D polymer
A1 García Arroyo, Paloma
A1 Segura Castedo, José Luis
A1 Navalpotro, Paula
A1 Mancheño, María J.
A1 Salagre, Elena
A1 Cabrera Trujillo, Jorge J.
A1 G. Michel, Enrique
A1 Carretero González, Javier
AB A novel two-dimensional polymer network (DAPT-TFP) has been synthesized based on pyrenetetraone moieties connected through robust enamine functional groups. Results show that DAPT-TFP exhibit high thermal and chemical stability, even after subjecting the material to a basic or acidic media for certain time (1 M H2SO4 or 1 M NaOH, respectively). An application to conductive additive-free electrode is detailed, as a proof of the ideal interaction between the ions of the neutral aqueous electrolyte and the molecular polymer nanostructure activated by simple acidic treatment. Thus, the study indicates that the redox properties of new organic electrode materials exhibiting limited electroactive properties can be boosted by a straightforward acidic treatment.
PB Elsevier
YR 2021
FD 2021-01-06
LK https://hdl.handle.net/20.500.14352/130442
UL https://hdl.handle.net/20.500.14352/130442
LA eng
NO Paloma García-Arroyo, Paula Navalpotro, María J. Mancheño, Elena Salagre, Jorge J. Cabrera-Trujillo, Enrique G. Michel, José L. Segura, Javier Carretero-González, Acidic triggering of reversible electrochemical activity in a pyrenetetraone-based 2D polymer, Polymer, Volume 212, 2021, 123273, ISSN 0032-3861, https://doi.org/10.1016/j.polymer.2020.123273.
NO Comunidad de Madrid
NO Ministerio de Ciencia, Innovación y Universidades
DS Docta Complutense
RD 19 ene 2026