%0 Journal Article
%A Alonso Gómez, José Miguel
%A Muñoz, María Paz
%T Platinum and Gold Catalysis: à la Carte Hydroamination of Terminal Activated Allenes with Azoles
%D 2019
%@ 1523-7060
%U https://hdl.handle.net/20.500.14352/92460
%X Nucleophilic additions to allenes catalyzed by transition metals represent a powerful tool to obtain selective access to diverse structures with numerous applications. Reported here is a straightforward methodology to achieve selective addition of azoles to the proximal or distal carbon of activated allenes depending on the catalyst used, unravelling a gold–platinum bimetallic catalysis approach for the 1,3-double addition of azoles to activated allenes to give 1,3-bisazole derivatives, an important scaffold in medicinal and organometallic chemistry.
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