RT Journal Article
T1 Platinum and Gold Catalysis: à la Carte Hydroamination of Terminal Activated Allenes with Azoles
A1 Alonso Gómez, José Miguel
A1 Muñoz, María Paz
AB Nucleophilic additions to allenes catalyzed by transition metals represent a powerful tool to obtain selective access to diverse structures with numerous applications. Reported here is a straightforward methodology to achieve selective addition of azoles to the proximal or distal carbon of activated allenes depending on the catalyst used, unravelling a gold–platinum bimetallic catalysis approach for the 1,3-double addition of azoles to activated allenes to give 1,3-bisazole derivatives, an important scaffold in medicinal and organometallic chemistry.
PB American Chemical Society
SN 1523-7060
YR 2019
FD 2019
LK https://hdl.handle.net/20.500.14352/92460
UL https://hdl.handle.net/20.500.14352/92460
LA eng
NO Alonso, José Miguel, y María Paz Muñoz. «Platinum and Gold Catalysis: À La Carte Hydroamination of Terminal Activated Allenes with Azoles». Organic Letters, vol. 21, n.o 18, septiembre de 2019, pp. 7639-44. https://doi.org/10.1021/acs.orglett.9b02949.
NO University of East Anglia (Reino Unido)
NO The Leverhulme Trust (Reino Unido)
DS Docta Complutense
RD 6 oct 2024