RT Journal Article T1 Critical role of two-dimensional island-mediated growth on the formation of semiconductor heterointerfaces A1 Luna, Esperanza A1 Guzmán, Álvaro A1 Trampert, Achim A1 Álvarez Silvar, Gabriel AB We experimentally demonstrate a sigmoidal variation of the composition profile across semiconductor heterointerfaces. The wide range of material systems (III-arsenides, III-antimonides, III-V quaternary compounds, III-nitrides) exhibiting such a profile suggests a universal behavior. We show that sigmoidal profiles emerge from a simple model of cooperative growth mediated by two-dimensional island formation, wherein cooperative effects are described by a specific functional dependence of the sticking coefficient on the surface coverage. Experimental results confirm that, except in the very early stages, island growth prevails over nucleation as the mechanism governing the interface development and ultimately determines the sigmoidal shape of the chemical profile in these two-dimensional-grown layers. In agreement with our experimental findings, the model also predicts a minimum value of the interfacial width, with the minimum attainable value depending on the chemical identity of the species. PB American Physical Society SN 0031-9007 YR 2012 FD 2012-09-18 LK https://hdl.handle.net/20.500.14352/43692 UL https://hdl.handle.net/20.500.14352/43692 LA eng NO © American Physical Society DS Docta Complutense RD 20 abr 2025