RT Book, Whole T1 Transition-metal-free synthesis of amines from nitrosoarenes: C-N cross-coupling reaction of nitroso compounds with boronic acids A1 García Csaky, Aurelio A1 Roscales García, Silvia AB Aromatic amines are compounds that have found widespread use in medicinal applications and materials science; consequently, their manufacture is one of the fastest-growing sectors in the chemical industry worldwide. The current trend in the industry is cost reduction and environmental compliance (sustainability); for that reason, the demand for new, green, and economic methods for the synthesis of these compounds has been intensified. This book provides a detailed description of a new method for the synthesis of functionalized secondary arylamines starting from nitrosoarenes and boronic acids in the presence of triethyl phosphite under metal-free-conditions. The plethora of research substained in the book will provide a detailed outlook on synthetic applications of this cross-coupling reaction and will open new horizons to extend the methodology development. The operational ease, broad functional group tolerance and scalability of the reaction make it suitable for adoption in both academic and industrial settings. The book should be specially useful to chemists or anyone else who may be interested in the synthesis of amines or in the reactivity of nitrosoarenes or boronic acids. PB Lambert Academic Publishing SN 978-62-003-0642-5 YR 2019 FD 2019-09-09 LK https://hdl.handle.net/20.500.14352/113009 UL https://hdl.handle.net/20.500.14352/113009 LA eng NO Ministerio de Ciencia, Innovacioón y Universidades DS Docta Complutense RD 17 jun 2025