%0 Journal Article
%A Nieto Simón, Juan Andrés
%A González Barrios, Marta María
%A Gómez Herrero, Adrián
%A Fernández-Díaz, María Teresa
%A Prado Gonjal, Jesús de la Paz
%A Castillo-Martínez, Elizabeth
%T Exploring hollandite-type K y V x Ti8- xO16 (0.25 ≤ x ≤ 2) as electrode materials in potassium-ion batteries (KIBs)
%D 2025
%U https://hdl.handle.net/20.500.14352/133962
%X Hollandite-type oxides, KyVxTi8-xO16, x = 0.25, 0.5, 0.75, 1, 1.25, 1.5, and 2, are synthesized via the citrate method and evaluated as potential electrode materials for potassium-ion batteries (KIBs). Neutron powder diffraction (NPD) confirms an undistorted I4/m structure, uniform K content (1.4 ≤ y ≤ 1.6), and high potassium isotropic displacement parameter (Biso). This decreases significantly for x ≥ 1, correlating with tunnel narrowing and vanadium's stronger polarization. Transmission electron microscopy (TEM) techniques, including selected area electron diffraction (SAED), annular bright field (ABF), and high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) identify superstructure reflections assigned to potassium/vacancy short-range order along the c axis with disorder between tunnels. Magnetic studies reveal paramagnetic behavior down to 2 K, with antiferromagnetic interactions at low temperature except for x = 0.25 composition, which exhibits ferromagnetic interactions. The experimental magnetic moment suggests a low Ti3+ content, with notable deviations at x = 1.25. The electrochemical performance is assessed via galvanostatic cycling using 2.5 M potassium bis(fluorosulfonyl)imide (KFSI) in triethyl phosphate (TEP) as electrolyte. At a rate of C/10, 2 K+ are reversibly de/inserted per formula unit, comparable to K0.17TiO2. At C/5, K1.5V0.75Ti7.25O16 demonstrates a reversible de/insertion of 1 K+/f.u., highlighting its potential for rechargeable KIBs
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