%0 Journal Article
%A Kubisz, M.
%A Fernández López, Israel
%A Hadlington, T. J.
%T Catalyst-free insertion of carbon monoxide into terminal Mg–C(sp3) bonds
%D 2026
%U https://hdl.handle.net/20.500.14352/134908
%X We describe the catalyst-free Insertion of carbon monoxide (CO) into magnesium alkyl bonds, leading exclusively to enediolate compounds through C–C coupling. Computational investigations suggest a metallated ketene intermedate. Ultimately, the formed enedoliate fragment can be liberated on reaction with a silane, establishing a potential pathway for s-block metal alkyl formylation catalysis.
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