RT Journal Article
T1 Catalyst-free insertion of carbon monoxide into terminal Mg–C(sp3) bonds
A1 Kubisz, M.
A1 Fernández López, Israel
A1 Hadlington, T. J.
AB We describe the catalyst-free Insertion of carbon monoxide (CO) into magnesium alkyl bonds, leading exclusively to enediolate compounds through C–C coupling. Computational investigations suggest a metallated ketene intermedate. Ultimately, the formed enedoliate fragment can be liberated on reaction with a silane, establishing a potential pathway for s-block metal alkyl formylation catalysis.
PB RSC
YR 2026
FD 2026-03-07
LK https://hdl.handle.net/20.500.14352/134908
UL https://hdl.handle.net/20.500.14352/134908
LA eng
NO Kubisz, M., et al. «Catalyst-Free Insertion of Carbon Monoxide into Terminal Mg–C(Sp3 ) Bonds». Chemical Communications, vol. 62, n.o 29, 2026, pp. 7519-23. DOI.org (Crossref), https://doi.org/10.1039/D6CC00736H.
NO Ministerio de Ciencia e Inovación (España)
NO Agencia Estatal de Investigación (España)
DS Docta Complutense
RD 28 abr 2026