RT Journal Article T1 Native Oxide Layer Role during Cryogenic-Temperature Ion Implantations in Germanium A1 Caudevilla Gutiérrez, Daniel A1 Pérez Zenteno, Francisco José A1 Duarte Cano, Sebastián A1 Algaidy, Sari A1 Benítez Fernández, Rafael A1 Godoy Pérez, Guillermo A1 Olea Ariza, Javier A1 San Andrés Serrano, Enrique A1 García Hernansanz, Rodrigo A1 Prado Millán, Álvaro Del A1 Martil De La Plaza, Ignacio A1 Pastor Pastor, David A1 García Hemme, Eric AB Herein, the structural properties and chemical composition of Ge samples implanted with tellurium at cryogenic temperatures are analyzed, focusing on the role of the native oxide. For germanium, cryogenic-temperature implantation is a requirement to achieve hyperdoped impurity concentrations while simultaneously preventing surface porosity. In this work, the critical role of the thin native germanium oxide is demonstrated when performing ion implantations at temperatures close to the liquid nitrogen temperature. The structural and chemical composition of tellurium-implanted samples as a function of the implanted dose from 5 × 1014 to 5 × 1015 cm−2 is analyzed. After a laser melting process, the incorporated oxygen is diffused to the surface forming again a GeOx layer which retains a large fraction of the total implanted dose. These detrimental effects can be eliminated by a selective etching of the native oxide layer prior to the ion implantation process. These effects have been also observed when implanting on Si substrates. This work identifies key aspects for conducting implantations at cryogenic temperatures, that are otherwise negligible for ion implanting at room temperature. PB Wiley YR 2024 FD 2024-07-08 LK https://hdl.handle.net/20.500.14352/110956 UL https://hdl.handle.net/20.500.14352/110956 LA eng NO Caudevilla, D., Pérez‐Zenteno, F. J., Duarte‐Cano, S., Algaidy, S., Benítez‐Fernández, R., Godoy‐Pérez, G., Olea, J., San Andrés, E., García‐Hernansanz, R., Del Prado, Á., Mártil, I., Pastor, D., & García‐Hemme, E. (2024). Native oxide layer role during cryogenic‐temperature ion implantations in germanium. Physica Status Solidi (a), 2400124. https://doi.org/10.1002/pssa.202400124 NO Agencia Española de Investigación NO Ministerio de Ciencia, Innovación y Universidades (España) NO Consejo Nacional de Humanidades, Ciencias y Tecnologías (México) NO Universidad Complutense de Madrid NO Ministry of Education (Saudi Arabia) NO Ministerio de Trabajo y Economía Social. (España) DS Docta Complutense RD 9 abr 2025