RT Journal Article
T1 Cyclobuteno[60]fullerenes as efficient n-type organicsemiconductors
A1 Reboredo, Silvia
A1 Girón, Rosa M.
A1 Filippone, Salvatore
A1 Mikie, Tsubasa
A1 Sakurai, Tsuneaki
A1 Seki, Shu
A1 Martín, Nazario
AB Cyclobuteno[3,4:1,2][60]fullerenes have been prepared in a straightforward manner by a simple reaction between [60]fullerene and readily available allenoates or alkynoates as organic reagents under basic and mild conditions. The chemical structure of the new modified fullerenes has been determined by standard spectroscopic techniques and confirmed by X-Ray diffraction analysis. Some of these new fullerene derivatives exhibit a remarkable intrinsic electron mobility – determined by using flash-photolysis time-resolved microwave conductivity (FP-TRMC) measurements – which surpasses that of the well-known PCBM, thus behavi ng as promising n-type organic semiconductors.
PB Wiley
SN 0947-6539
YR 2016
FD 2016-09
LK https://hdl.handle.net/20.500.14352/17676
UL https://hdl.handle.net/20.500.14352/17676
LA eng
NO Unión Europea. FP7
NO Ministerio de Economía y Competitividad (MINECO)
NO Comunidad de Madrid
DS Docta Complutense
RD 6 abr 2025