TY - JOUR AU - Toledano Pinedo, Mireia AU - Martínez Del Campo, Teresa AU - Yanai, Hikaru AU - Almendros, Pedro PY - 2022 DO - 10.1021/acscatal.2c03858 UR - https://hdl.handle.net/20.500.14352/104913 T2 - ACS Catalysis AB - A gold-catalyzed bis[(trifluoromethyl)sulfonyl]ethylation of α-allenols, which allows the preparation of sterically congested bis(triflyl)enals bearing quaternary carbon centers, is presented. This sequence differs from the conventional reaction... LA - eng M2 - 11675 PB - ACS Publications KW - allenes KW - gold π-Lewis base catalyst KW - quaternary center KW - selectivity TI - Au(I) as a π‑Lewis Base Catalyst: Controlled Synthesis of Sterically Congested Bis(triflyl)enals from α‑Allenols TY - journal article VL - 12 ER -