RT Journal Article
T1 Wireless Nano Irradiance Meter Based on UpconversionLuminescence Lifetime
A1 Casillas Rubio, Alejandro
A1 Laurenti, Marco
A1 Cascales, Juan Pedro
A1 Gómez Calderón, Óscar
A1 Méndez González, Diego
AB Measuring light irradiance, or power density, within a material is essential for ensuring the precision, efficiency, and safety of light-based technologies, such as photodynamic therapies, optical sensing, and material processing. However, this task becomes particularly challenging in scenarios involving highly scattering or absorbing media, dynamic systems with varying properties, or confined and hardly accessible compartments. These challenges can be addressed by using colloidal luminescent nanomaterials with luminescence lifetimes strongly dependent on excitation irradiance. Building on this, an upconversion lifetime-based Nano Irradiance Meter (nIM) is proposed, employing, on SrYb3 +F5:@CaF2 upconverting nanoparticles. This nIM operates within the first biological window and allows the direct estimation of laser irradiance, without prior knowledge of the area illuminated by the excitation beam. The feasibility of the sensor is validated through a calibration process, correlating the lifetime of the 770 nm upconversion luminescence of Tm3 + ions with the 967 nm excitation irradiance. The sensor achieved a sensitivity of 0.9% W−1 cm2 at low irradiances (≈17 W cm−2) and 0.008% W−1 cm2 at high irradiances (≈5 kW cm−2), surpassing previously reported results based on ratiometric luminescence approaches. Finally, its robust performance under real-life conditions across various media is demonstrated.
PB Wiley
YR 2025
FD 2025-06
LK https://hdl.handle.net/20.500.14352/122560
UL https://hdl.handle.net/20.500.14352/122560
LA eng
NO A. Casillas-Rubio, M. Laurenti, J. P. Cascales, O. G. Calderón, D. Mendez-Gonzalez, S. Melle, Wireless Nano Irradiance Meter Based on Upconversion Luminescence Lifetime. Adv. Optical Mater. 2025, 2500093. https://doi.org/10.1002/adom.202500093
NO Ministerio de Ciencia e Innovación (España)
NO Comunidad de Madrid
NO Universidad Complutense de Madrid
DS Docta Complutense
RD 26 dic 2025