RT Journal Article
T1 Selective Functionalization of Achmatowicz Rearrangement  Products by Reactions with Potassium Organotrifluoroborates  under Transition-Metal-Free Conditions
A1 Roscales García, Silvia
A1 Ortega Garrido, Víctor
A1 García Csaky, Aurelio
AB The repertoire of synthetic transformations of the products of the Achmatowicz rearrangement has been expanded by exploring their reactivity with potassium organotrifluoroborates in the absence of transition metals. Depending on the reaction conditions and the substitution pattern of the starting material, the reaction may lead to the stereoselective synthesis of dihydropyranones (2,6-trans), tetrahydropyranones (2,3-cis-2,6-cis) or functionalized 1,4-dicarbonyl compounds. The method has also been adapted for the one-pot synthesis of functionalized pyrroles.
PB ACS
YR 2018
FD 2018
LK https://hdl.handle.net/20.500.14352/125561
UL https://hdl.handle.net/20.500.14352/125561
LA eng
NO Roscales, Silvia, et al. «Selective Functionalization of Achmatowicz Rearrangement Products by Reactions with Potassium Organotrifluoroborates under Transition-Metal-Free Conditions». The Journal of Organic Chemistry, vol. 83, n.o 18, septiembre de 2018, pp. 11425-36. DOI.org (Crossref), https://doi.org/10.1021/acs.joc.8b01643.
NO Ministerio de Ciencia, Innovación y Universidades
DS Docta Complutense
RD 8 abr 2026