RT Journal Article T1 In situ generation of 3D graphene-like networks from cellulose nanofibres in sintered ceramics A1 Kocjan, Andraz A1 Schmidt, Rainer A1 Lazar, Ana A1 Prado-Gonjal, Jesus A1 Prado Gonjal, Jesús De La Paz A1 Kovac, Janez A1 Logar, Manca A1 Mompean, Francisco J A1 García-Hernández, Mar A1 Ruiz-Hitzky, Eduardo A1 Wicklein, Bernd AB Establishing a 3D electrically percolating network in an insulating matrix is key to numerous engineering and functional applications. To this end, using hydrophobic carbon nanofillers is tempting, but still results in suboptimal performance due to processing challenges. Here, we demonstrate how natural cellulose nanofibres can be in situ transformed into graphene-like sheets connected to a 3D network enhancing both the transport and the mechanical properties of sintered engineering ceramics. The network architecture also permits the decoupling of electrical and thermal conductivities, which represents a major obstacle in attaining efficient thermoelectric materials. We foresee that our transferable methodology can pave the way for the use of natural nanofibres to unravel the full potential of 3D graphene-like networks to accelerate development in fields like energy and telecommunications. PB Royal Society of Chemistry SN 2040-3364 YR 2018 FD 2018-04-27 LK https://hdl.handle.net/20.500.14352/93984 UL https://hdl.handle.net/20.500.14352/93984 LA eng NO Kocjan, A., Schmidt, R., Lazar, A., Prado-Gonjal, J., Kovač, J., Logar, M., ... & Wicklein, B. (2018). In situ generation of 3D graphene-like networks from cellulose nanofibres in sintered ceramics. Nanoscale, 10(22), 10488-10497. NO Está depositada la versión postprint del artículo NO Slovenian Research Agency - Slovenia NO Ministerio de Economía y Competitividad (España) NO Unión Europea Horizonte 2020 DS Docta Complutense RD 7 oct 2024