RT Journal Article T1 Vein-type graphite in Jurassic volcanic rocks of the external zone of the Betic Cordillera, Southern Spain. A1 Barrenechea, José F. A1 Luque del Villar, Francisco Javier A1 Rodas, Magdalena A1 Pasteris, Jill D. AB We have investigated volcanic-rock-hosted graphitem in eralization in the Huelma area of the Betic Cordillera, in southern Spain, in order to establish the mineralogical characteristics of the graphite andthe mechanism of its formation. The graphite is highlycrystalline, asrevealed by XRDandRaman spectroscopic data, andrelatively pure chemically (C content >90wt.%). XRD data demonstrate that some of themineralized bodies contain both hexagonal and rhombohedral graphite. Carbon isotopic compositions (-23.0< δ13 C <-20.7 ‰ ) and other geological observations indicate that thecarbon in the graphite was derived from organic matter included in the metamorphic basement. Cooling of a C-O-H fluid appears to be the most likely mechanism for precipitation of the graphite, although hydration reactions also may have played a role. The presence of rhombohedralgraphiteis discussed with reference to the kinetics of graphite formation. PB Mineralogical Association of Canada SN 0008-4476 YR 1997 FD 1997 LK https://hdl.handle.net/20.500.14352/58158 UL https://hdl.handle.net/20.500.14352/58158 LA eng DS Docta Complutense RD 2 may 2024