%0 Journal Article
%A Sánchez Ahijón, Elena
%A Marín Gamero, Rafael
%A Molero-Sánchez, Beatriz
%A Ávila Brande, David
%A Manjón-Sanz, Alicia
%A Fernández-Díaz, M. Teresa
%A Morán Miguélez, Emilio
%A Schmidt, Rainer
%A Prado Gonjal, Jesús de la Paz
%T From theory to experiment: BaFe0.125Co0.125Zr0.75O3−δ, a highly promising cathode for intermediate temperature SOFCs
%D 2020
%@ 2050-7488
%U https://hdl.handle.net/20.500.14352/95885
%X In a recent theoretical study [Jacobs et al., Adv. Energy Mater., 2018, 8, 1702708], BaFe0.125Co0.125Zr0.75O3−δ was predicted to be a stable phase with outstanding performance as an auspicious cathode for intermediate-temperature solid oxide fuel cells (IT-SOFCs). It is shown here that the theoretical predictions are valid. The material can be synthesized by the citrate method as a single cubic Pm[3 with combining macron]m phase with a significant amount of oxygen vacancies, randomly distributed in the anionic sublattice facilitating oxygen vacancy conduction. A thermal expansion coefficient of 8.1 × 10−6 K−1 suggests acceptable compatibility with common electrolytes. Electrochemical impedance spectroscopy of symmetrical cells gives an area-specific resistance of 0.33 Ω cm2 at 700 °C and 0.13 Ω cm2 at 800 °C. These values are reduced to 0.13 Ω cm2 at 700 °C and 0.05 Ω cm2 at 800 °C when the material is mixed with 30 wt% Ce0.9Gd0.1O2−δ.
%~