RT Journal Article
T1 Reduction of Grain Boundary Resistance of La0.5Li0.5TiO3 bythe Addition of Organic Polymers
A1 Boyano, Iker
A1 Mainar, Aroa R.
A1 Blázquez, J. Alberto
A1 Kvasha, Andriy
A1 Bengoechea, Miguel
A1 Meatza, Iratxe de
A1 García Martín, Susana
A1 Varez Álvarez, Alejandro
A1 Sanz, Jesús
A1 García Alvarado, Flaviano
AB The organic solvents that are widely used as electrolytes in lithium ion batteries present safety challenges due to their volatile and flammable nature. The replacement of liquid organic electrolytes by non-volatile and intrinsically safe ceramic solid electrolytes is an effective approach to address the safety issue. However, the high total resistance (bulk and grain boundary) of such compounds, especially at low temperatures, makes those solid electrolyte systems unpractical for many applications where high power and low temperature performance are required. The addition of small quantities of a polymer is an efficient and low cost approach to reduce the grain boundary resistance of inorganic solid electrolytes. Therefore, in this work, we study the ionic conductivity of different composites based on non-sintered lithium lanthanum titanium oxide (La0.5Li0.5TiO3) as inorganic ceramic material and organic polymers with different characteristics, added in low percentage (<15 wt.%). The proposed cheap composite solid electrolytes double the ionic conductivity of the less cost-effective sintered La0.5Li0.5TiO3.
PB MDPI
SN 2079-4991
YR 2021
FD 2021
LK https://hdl.handle.net/20.500.14352/7896
UL https://hdl.handle.net/20.500.14352/7896
LA eng
NO Ministerio de Ciencia e Innovación (MICINN)
NO Ministerio de Ciencia e Innovación (MICINN)/CDTI
NO Ministerio de Ciencia e Innovación (MICCIN)/FEDER
DS Docta Complutense
RD 30 abr 2024