RT Journal Article T1 Negishi reaction in BODIPY dyes. Unprecedented alkylation by palladium-catalyzed C–C coupling in boron dipyrromethene derivatives A1 Durán Sampedro, Gonzalo A1 Palao, Eduardo A1 Rodríguez Agarrabeitia, Antonia A1 Moya Cerero, Santiago de la A1 Boens, Noël A1 Ortiz García, María Josefa AB Negishi reactions of 3-halogen and 3,5-dihalogen substituted BODIPYs with different organozinc reagents are reported as the first examples of this valuable palladium-catalyzed C–C coupling reaction into the family of the BODIPY dyes. It is demonstrated that the Negishi coupling is especially useful for obtaining interesting alkylated BODIPYs, including synthetically-valuable asymmetrically-3,5-disubstituted BODIPYs. PB Royal Society of Chemistry SN 2046-2069 YR 2014 FD 2014 LK https://hdl.handle.net/20.500.14352/98895 UL https://hdl.handle.net/20.500.14352/98895 LA eng NO Durán Sampedro, G., Palao, E., Rodríguez Agarrabeitia, A. et al. «Negishi Reaction in BODIPY Dyes. Unprecedented Alkylation by Palladium-Catalyzed C–C Coupling in Boron Dipyrromethene Derivatives». RSC Adv., vol. 4, n.o 37, 2014, pp. 19210-13. https://doi.org/10.1039/C4RA00651H. NO Ministerio de Economía, Comercio y Empresa (España) DS Docta Complutense RD 14 may 2025