RT Journal Article
T1 Rational molecular design enhancing the photonic performance of red-emitting perylene bisimide dyes
A1 Avellanal Zaballa, Edurne
A1 Durán Sampedro, Gonzalo
A1 Prieto Castañeda, Alejandro
A1 Rodríguez Agarrabeitia, Antonia
A1 García Moreno, Inmaculada
A1 López Arbeloa, Íñigo María
A1 Bañuelos Prieto, Jorge
A1 Ortiz García, María Josefa
AB We report the synthesis of novel multichromophoric organic architectures, where perylene red is decorated with BODIPY and/or hydroxycoumarin dyes acting as light harvesters and energy donors. The computationally-aided photophysical study of these molecular assemblies reveals a broadband absorption which, regardless of the excitation wavelength, leads solely to a bright red-edge emission from perylene bisimide after efficient intramolecular energy transfer hops. The increase of the absorbance of these molecular antennas at key pumping wavelengths enhances the laser action of the commercial perylene red. The herein applied strategy based on energy transfer dye lasers should boost the use of perylene-based dyes as active media for red-emitting lasers.
PB Royal Society of Chemistry
SN 1463-9076
YR 2017
FD 2017-04-25
LK https://hdl.handle.net/20.500.14352/18148
UL https://hdl.handle.net/20.500.14352/18148
LA eng
NO Avellanal-Zaballa, E., Durán Sampedro, G., Proeto Castañeda, A. et al. «Rational Molecular Design Enhancing the Photonic Performance of Red-Emitting Perylene Bisimide Dyes». Physical Chemistry Chemical Physics, vol. 19, n.o 20, mayo de 2017, pp. 13210-18. pubs.rsc.org, https://doi.org/10.1039/C7CP01626C.
NO Ministerio de Ciencia, Innovación y Universidades (España)
NO Gobierno Vasco
DS Docta Complutense
RD 1 sept 2024