RT Journal Article
T1 Femtosecond photodissociation dynamics of chloroiodomethane in the first absorption band
A1 Murillo Sánchez, Marta Luisa
A1 Marggi Poullaín, Sonia
A1 González-Vázquez, Jesús
A1 Corrales, Maria Eugenia
A1 Balerdi, Garikoitz
A1 Bañares Morcillo, Luis
AB The real time photodissociation of chloroiodomethane (CH2ICl) in the first absorption band at 268 nm is reported in comparison with the well-known methyl iodide (CH3I) in order to investigate the halogen-atom substituent effect on the time-resolved photodynamics of halomethanes. Femtosecond velocity map imaging measurements in conjunction with resonance enhanced multiphoton ionization (REMPI) to detect the iodine fragments have been performed to obtain translational energy, angular distributions and the photodissociation reaction times. High level ab initio and on-the-fly trajectory calculations have been carried out to rationalize the experimental results in terms of the excited states involved and the dissociation mechanisms.
SN 0009-2614
YR 2017
FD 2017
LK https://hdl.handle.net/20.500.14352/95481
UL https://hdl.handle.net/20.500.14352/95481
LA eng
NO Murillo-Sánchez, M. L., et al. «Femtosecond Photodissociation Dynamics of Chloroiodomethane in the First Absorption Band». Chemical Physics Letters, vol. 683, septiembre de 2017, pp. 22-28. https://doi.org/10.1016/j.cplett.2017.02.037.
NO Universidad Complutense de Madrid
NO Ministerio de Economía y Competitividad (España)
DS Docta Complutense
RD 17 abr 2025