RT Journal Article
T1 Development of homogeneous and heterogenized rhodium(i) and palladium(ii) complexes with ligands based on a chiral proton sponge building block and their application as catalysts
A1 Villaverde Cantizano, Gonzalo
A1 Arnanz, Avelina
A1 Iglesias, Marta
A1 Monge, Ángeles
A1 Sánchez, Félix
A1 Snejko, Natalia
AB Chiral compounds prepared from proton sponge building block 8-((2R,5R)-2,5-dimethylpyrrolidin-1-yl)naphthalen-1-amine were found to be effective chiral ligands for obtaining complexes of rhodium(I) and palladium(II) by reaction with [RhCl(cod)]2, PdCl2(cod) or Pd(OAc)2. The complexes bearing triethoxysilane groups were immobilized on mesoporous MCM-41 in order to obtain new heterogeneous catalysts. Both materials are active in the hydrogenation of alkenes and could be recycled without loss of activity or enantioselectivity.
SN 1477-9226
YR 2011
FD 2011
LK https://hdl.handle.net/20.500.14352/98475
UL https://hdl.handle.net/20.500.14352/98475
LA eng
NO Villaverde, Gonzalo, et al. «Development of Homogeneous and Heterogenized Rhodium(i) and Palladium(Ii) Complexes with Ligands Based on a Chiral Proton Sponge Building Block and Their Application as Catalysts». Dalton Transactions, vol. 40, n.o 37, 2011, p. 9589. https://doi.org/10.1039/c1dt10597c.
DS Docta Complutense
RD 20 mar 2026