RT Journal Article
T1 Understanding the enhanced reactivity of strained intermolecular Frustrated Lewis Pairs
A1 Portela García de Blas, Susana
A1 Fernández López, Israel
AB The poorly understood factors controlling the enhancedreactivity of strained intramolecular frustrated Lewis pairs (FLPs) having a rigid biphenylene tether have been quantitatively explored in detail by means of computational methods. With the help of the activation strain model of reactivity and theenergy decomposition analysis methods, the challenging alleneactivation reaction has been selected and compared to theanalogous process mediated by a related intramolecular FLPhaving a more flexible tether, which is significantly less reactive.In addition, the influence of the nature of the Lewis acid atomon the reactivity of the strained FLP has been considered aswell showing that the reactivity steadily decreases when goingdown in group 13.
PB Wiley
SN 0044-2313
YR 2023
FD 2023
LK https://hdl.handle.net/20.500.14352/107898
UL https://hdl.handle.net/20.500.14352/107898
LA eng
NO S. Portela, I. Fernández, Z. Anorg. Allg. Chem. 2023, 649, e202200384.
DS Docta Complutense
RD 6 abr 2025