RT Journal Article T1 Transition-Metal-Free Direct anti-Carboboration of Alkynes with Boronic Acids To Produce Alkenylheteroarenes A1 Roscales García, Silvia A1 García Csaky, Aurelio AB The transition-metal-free intermolecular direct 1,2-carboboration reaction of heteroarylacetylenes using boronic acids as reagents is achieved by utilizing tartaric acid as promoter. The reaction proceeds with excellent regioselectivity and anti stereoselectivity to afford boroxole frameworks. The resulting compounds are of use for the stereoselective preparation of polysubstituted alkenylheteroarenes. PB American Chemical Society YR 2015 FD 2015 LK https://hdl.handle.net/20.500.14352/116175 UL https://hdl.handle.net/20.500.14352/116175 LA eng NO Roscales, Silvia, y Aurelio G. Csákÿ. «Transition-Metal-Free Direct Anti -Carboboration of Alkynes with Boronic Acids To Produce Alkenylheteroarenes». Organic Letters, vol. 17, n.o 6, marzo de 2015, pp. 1605-08. DOI.org (Crossref), https://doi.org/10.1021/acs.orglett.5b00517. NO Universidad Complutense de Madrid DS Docta Complutense RD 7 abr 2025