RT Journal Article
T1 Squeezing electrons out of 6s2 lone-pairs in perovskite-type oxides
A1 Wang, Chun-Hai
A1 Kayser González, Paula
A1 Kennedy, Brendan
A1 Maynard-Casely, Helen
A1 Gu, Qinfen
A1 Ling, Chris
AB Having identified a set of conditions that predispose a solid-state ionic compound to a pressure-induced valence transition, we investigated a series of Bi(III) perovskite oxides. We found such a transition below 10 GPa in every case, including one that we synthesised for the first time (double perovskite-type Ba2BiOsO6).
PB Royal Society of Chemistry
SN 1359-7345
YR 2019
FD 2019
LK https://hdl.handle.net/20.500.14352/92217
UL https://hdl.handle.net/20.500.14352/92217
LA eng
NO Wang, Chun-Hai, et al. «Squeezing Electrons out of 6s 2 Lone-Pairs in Perovskite-Type Oxides». Chemical Communications, vol. 55, n.o 27, 2019, pp. 3887-90. https://doi.org/10.1039/C8CC09608B.
DS Docta Complutense
RD 13 abr 2025