RT Journal Article T1 Tuning optical and electrical properties of zinc oxide PLD films: effect of temperature and air annealing A1 Ramos Justicia, Juan Francisco A1 Sotillo Buzarra, Belén A1 Urbieta Quiroga, Ana Irene A1 Gonzalo, J. A1 Fernández Sánchez, Paloma AB The effect of substrate temperature and post-deposition thermal annealing on the optical and electrical properties of ZnO thin films grown by pulsed laser deposition are studied. XRD analysis reveals a (002) orientation and stress relaxation with increasing growth temperature. AFM shows a granular surface topography, whose grains become larger after annealing. Competition of coalescence and recrystallisation mechanisms is proposed to explain these results. Optical transmission experiments reveal changes in the relative intensity of the defect bands in the visible region, caused by changes in the population of intrinsic defects. Electrical measurements find that room-temperature grown films are p-type, while higher-temperature deposited films are n-type, and all become p-type after annealing. Low-temperature measurements reveal a switch in the conductivity type from p-to n-type around 220–250 K depending on the samples, which is explained due to competing defect-related conduction mechanisms. PB Elsevier SN 0272-8842 YR 2026 FD 2026-01 LK https://hdl.handle.net/20.500.14352/133632 UL https://hdl.handle.net/20.500.14352/133632 LA eng NO J.F. Ramos-Justicia, B. Sotillo, A. Urbieta, J. Gonzalo, P. Fernández, Tuning optical and electrical properties of zinc oxide PLD films: effect of temperature and air annealing, Ceramics International 52 (2026) 1132–1140. https://doi.org/10.1016/j.ceramint.2025.11.418. NO 2025 Acuerdos transformativos CRUE-CSIC© 2025 The AuthorsPrograma de ayudas de Contratos Predoctorales CT15/23 NO European Commission NO Ministerio de Ciencia e Innovación (España) NO Agencia Estatal de Investigación (España) NO Universidad Complutense de Madrid NO Banco Santander DS Docta Complutense RD 18 mar 2026