RT Journal Article
T1 Hexakis-adducts of [60]fullerene as molecular scaffolds of polynuclear spin-crossover molecules
A1 Palacios-Corella, Mario
A1 Ramos-Soriano, Javier
A1 Souto, Manuel
A1 Ananias, Duarte
A1 Calbo, Joaquín
A1 Ortí, Enrique
A1 Illescas Martínez, Beatriz María
A1 Clemente-León, Miguel
A1 Martín León, Nazario
A1 Coronado, Eugenio
AB A family of hexakis-substituted [60]fullerene adducts endowed with the well-known tridentate 2,6-bis(pyrazol-1-yl)pyridine (bpp) ligand for spin-crossover (SCO) systems has been designed and synthesized. It has been experimentally and theoretically demonstrated that these molecular scaffolds are able to form polynuclear SCO complexes in solution. UV-vis and fluorescence spectroscopy studies have allowed monitoring of the formation of up to six Fe(II)–bpp SCO complexes. In addition, DFT calculations have been performed to model the different complexation environments and simulate their electronic properties. The complexes retain SCO properties in the solid state exhibiting both thermaland photoinduced spin transitions, as confirmed by temperature-dependent magnetic susceptibility and Raman spectroscopy measurements. The synthesis of these complexes demonstrates that [60]fullerene hexakis-adducts are excellent and versatile platforms to develop polynuclear SCO systems in which a fullerene core is surrounded by a SCO molecular shell.
PB Royal Society of Chemistry
SN 2041-6520
YR 2021
FD 2021
LK https://hdl.handle.net/20.500.14352/92809
UL https://hdl.handle.net/20.500.14352/92809
LA eng
NO Palacios-Corella, Mario, et al. «Hexakis-Adducts of [60]Fullerene as Molecular Scaffolds of Polynuclear Spin-Crossover Molecules». Chemical Science, vol. 12, n.o 2, 2021, pp. 757-66. https://doi.org/10.1039/D0SC05875K.
NO Ministry of Education and Science of Russian Federation
NO Comunitat Valenciana
NO European Commission
NO Ministerio de Ciencia e Universidades (España)
DS Docta Complutense
RD 17 abr 2025