RT Journal Article
T1 Effects of Oil Phase on the Inversion of Pickering Emulsions Stabilized by Palmitic Acid Decorated Silica Nanoparticles
A1 González González, Andrés
A1 Sánchez Arribas, Natalia
A1 Santini, Eva
A1 Rodríguez Villafuerte, José Luis
A1 Carbone, Carlo
A1 Ravera, Francesca
A1 Ortega Gómez, Francisco
A1 Liggieri, Libero
A1 Rubio, Ramón G.
A1 Guzmán Solís, Eduardo
AB Pickering emulsions stabilized by the interaction of palmitic acid (PA) and silica nanoparticles (SiNPs) at the water/oil interface have been studied using different alkane oil phases. The interaction of palmitic acid and SiNPs has a strong synergistic character in relation to the emulsion stabilization, leading to an enhanced emulsion stability in relation to that stabilized only by the fatty acid. This results from the formation of fatty acid-nanoparticle complexes driven by hydrogen bond interactions, which favor particle attachment at the fluid interface, creating a rigid armor that minimizes droplet coalescence. The comparison of emulsions obtained using different alkanes as the oil phase has shown that the hydrophobic mismatch between the length of the alkane chain and the C16 hydrophobic chain of PA determines the nature of the emulsions, with the solubility of the fatty acid in the oil phase being a very important driving force governing the appearance of phase inversion.
PB MPDI
SN 2504-5377
YR 2022
FD 2022-04-25
LK https://hdl.handle.net/20.500.14352/72494
UL https://hdl.handle.net/20.500.14352/72494
LA eng
NO Unión Europea. Horizonte 2020
NO Ministerio de Ciencia e Innovación (MICINN)
DS Docta Complutense
RD 6 oct 2024