RT Journal Article
T1 Interfacial Free Energy and Tolman Length of CurvedLiquid-Solid Interfaces from Equilibrium Studies
A1 Montero de Hijes, Pablo
A1 Espinosa, Jorge R.
A1 Bianco, Valentino
A1 Sanz García, Eduardo
A1 Vega de las Heras, Carlos
AB In this work, we study by means of simulations of hard spheres the equilibrium between a spherical solid cluster and the fluid. In the NVT ensemble we observe stable/metastable clusters of the solid phase in equilibrium with the fluid, representing configurations that are global/local minima of the Helmholtz free energy. Then, we run NpT simulations of the equilibrated system at the average pressure of the NVT run and observe that the clusters are critical because they grow/shrink with a probability of 1/2.Therefore, a crystal cluster equilibrated in the NVT ensemble corresponds to a Gibbs free energy máximum where the nucleus is in unstable equilibrium with the surrounding fluid, in accordance with what has been recently shown for vapor bubbles in equilibrium with the liquid. Then, within the Seeding framework, we use Classical Nucleation Theory to obtain both the interfacial free energy γ and the nucleation rate. The latter is in very good agreement with independent estimates using techniques that do not rely on Classical Nucleation Theory when the mislabeling criterion is used to identify the molecules of the solid cluster. We therefore argue that the radius obtained from the mislabeling criterion provides a good approximation for the radius of tension, R_s . We obtain an estimate of the Tolman length by extrapolating the difference between R e (the Gibbs dividing surface) and R s to infinite radius. We show that such definition of the Tolman length coincides with that obtained by fitting γ versus 1/R_s to a straight line as recently applied to hard spheres.
PB American Chemical Society (ACS)
SN 1932-7447
YR 2020
FD 2020
LK https://hdl.handle.net/20.500.14352/6169
UL https://hdl.handle.net/20.500.14352/6169
LA eng
NO Unión Europea. Horizonte 2020
NO Ministerio de Economía y Competitividad (MINECO)
NO Universidad Complutense de Madrid
DS Docta Complutense
RD 19 may 2024