RT Journal Article T1 Antioxidant capacity index based on gold nanoparticles formation. Application to extra virgin olive oil samples A1 Della Pelle, Flavio A1 Vilela García, Diana A1 González, María Cristina A1 Lo Sterzo, Claudio A1 Compagnone, Darío A1 Carlo, Michele Del A1 Escarpa, Alberto AB A simple gold nanoparticles (AuNPs) based colorimetric assay for the antioxidant activity determination has been developed. The AuNP formation is mediated by extra virgin olive oil (EVOO’s) endogenous polyphenols; the reaction is described by a sigmoidal curve. The ratio KAuNPs/Xc50 (slope of the linear part of the sigmoid/concentration at half value of the absorbance) was found to be the optimal parameter to report the antioxidant capacity with respect to the single KAuNPs or Xc50 values. The obtained data demonstrated that the compounds with ortho-diphenols functionality are most active in reducing gold (III) to gold (0). Thus, intermediate activity was found for gallic acid, while tyrosol (mono-phenols) had a significant lower activity than the others antioxidant compounds (at least one order of magnitude). In the analysis of olive oil samples, a significant correlation among classical methods used to determine antioxidant activity and the proposed parameter was found with R values in the 0.96–0.97 range. PB Elsevier SN 0308-8146 YR 2015 FD 2015 LK https://hdl.handle.net/20.500.14352/92158 UL https://hdl.handle.net/20.500.14352/92158 LA eng NO Della Pelle, Flavio, et al. «Antioxidant Capacity Index Based on Gold Nanoparticles Formation. Application to Extra Virgin Olive Oil Samples». Food Chemistry, vol. 178, julio de 2015, pp. 70-75. https://doi.org/10.1016/j.foodchem.2015.01.045. NO Ministerio de Economía y Competitividad (España) NO Ministerio de Ciencia e Innovación (España) NO Comunidad de Madrid NO Fondazione Tercas (Italia) NO Universidad de Teramo (Italia) DS Docta Complutense RD 21 dic 2025