RT Journal Article
T1 Control defeasance by anti-alignment in the excited state
A1 Chang, Bo Y
A1 Shin, Seokmin
A1 González Vázquez, Jesús
A1 Martín, Fernando
A1 Malinovsky, Vladimir S
A1 Sola, Ignacio R
AB We predict anti-alignment dynamics in the excited state of H2+ or related homonuclear dimers in the presence of a strong field. This effect is a general indirect outcome of the strong transition dipole and large polarizabilities typically used to control or to induce alignment in the ground state. In the excited state, however, the polarizabilities have the opposite sign compared to those in the ground state, generating a torque that aligns the molecule perpendicular to the field, deeming any laser-control strategy impossible.
YR 2019
FD 2019
LK https://hdl.handle.net/20.500.14352/113844
UL https://hdl.handle.net/20.500.14352/113844
LA eng
NO Chang BY , Shin S , González-Vázquez J , Martín F , Malinovsky VS , Sola IR . Control defeasance by anti-alignment in the excited state. Phys Chem Chem Phys. 2019 Nov 14;21(42):23620-23625. doi: 10.1039/c9cp04427b. Epub 2019 Oct 18. PMID: 31624812.
NO Ministerio de Economía, Comercio y Empresa
NO Comunidad de Madrid
DS Docta Complutense
RD 19 mar 2026