RT Journal Article
T1 Exploring the Application of the Negishi Reaction of HaloBODIPYs: Generality, Regioselectivity, and Synthetic Utility in the Development of BODIPY Laser Dyes
A1 Palao Utiel, Eduardo
A1 Durán Sampedro, Gonzalo
A1 Moya Cerero, Santiago de la
A1 Madrid, Miriam
A1 García López, Carmen
A1 Rodríguez Agarrabeitia, Antonia
A1 Verbelen, Bram
A1 Dehaen, Wim
A1 Boens, Nöel
A1 Ortiz García, María Josefa
AB The generality of the palladium-catalyzed C–C coupling Negishi reaction when applied to haloBODIPYs is demonstrated on the basis of selected starting BODIPYs, including polyhalogenated and/or asymmetrical systems, and organozinc reagents. This reaction is an interesting synthetic tool in BODIPY chemistry, mainly because it allows a valuable regioselective postfunctionalization of BODIPY chromophores with different functional groups. In this way, functional patterns that are difficult to obtain by other procedures (e.g., asymmetrically functionalized BODIPYs involving halogenated positions) can now be made. The regioselectivity is achieved by controlling the reaction conditions and is based on almost-general reactivity preferences, and the nature of the involved halogens and their positions. This ability is exemplified by the preparation of a series of new BODIPY dyes with unprecedented substitution patterns allowing noticeable lasing properties.
PB ACS
PB Amiceran Chemical Society
SN 0022-3263 (Print) 1520-6904(Online)
YR 2016
FD 2016-05-06
LK https://hdl.handle.net/20.500.14352/23410
UL https://hdl.handle.net/20.500.14352/23410
LA eng
NO Ministerio de Ciencia, Innovación y Universidades (España)
NO Ministerie voor Wetenschapsbeleid (Bélgica)
DS Docta Complutense
RD 9 abr 2025