RT Journal Article T1 Scanning tunnelling microscopy and spectroscopy of nanocrystalline silicon films A1 Nogales Díaz, Emilio A1 Méndez Martín, María Bianchi A1 Piqueras De Noriega, Francisco Javier A1 Plugaru, R AB Scanning tunnelling microscopy (STM) has been sometimes applied in recent years to characterize porous silicon. In contrast, other forms of light emitting Si, such as nanocrystalline silicon films, prepared by different methods, have not been, or are only occasionally, studied by STM related techniques. In this paper STM and spectroscopy measurements have been performed on nanocrystalline silicon films obtained by low pressure chemical vapour deposition followed by boron implantation. Subsequent annealing of the samples caused an increase of the crystallites size. Scanning tunnelling spectroscopy enabled us to determine the surface band gap in films. In all annealed nanocrystalline films the value of this gap is similar to the value in bulk Si. However, a large value of the gap, of about 4.5 eV, is measured in as-implanted films. The different behaviour is explained in terms of a quantum confinement effect related to the nanocrystal's size. PB Iop Publishing Ltd SN 0268-1242 YR 2001 FD 2001-09 LK https://hdl.handle.net/20.500.14352/58934 UL https://hdl.handle.net/20.500.14352/58934 LA eng NO © 2001 IOP Publishing Ltd.This work was supported by DGES (PB96-0639) and by the Scientific Cooperation Program between Spain and Romania. NO DGES NO Scientific Cooperation Program between Spain and Romania DS Docta Complutense RD 11 abr 2025