%0 Journal Article
%A Rubio, Pedro
%A Salazar, Ainhoa
%A Durán Sampedro, Gonzalo
%A Torre, Gema de la
%T Synthesis, aggregation, and photophysical properties of amphiphilic BODIPY-Pt(II) metallacycles
%D 2023
%@ 1088-4246
%U https://hdl.handle.net/20.500.14352/95440
%X The construction of metallo-organic macrocycles using transition metals and optoelectronically active donor ligands is a very active area of research due to the potential applicability of these structures as sensors or as drugs for combined photodynamic/chemotherapy treatments. Herein, we report on the synthesis, photophysical properties, and aggregation behavior of a triangular Pt(II)-assembled metallo-supramolecular complex built by the coordination-driven assembly of a BODIPY functionalized with two pyridines at the 2,6 positions and an (R, R)-phenylalanine dipeptide moiety in the meso position. This hydrophilic group provides the metallacycle with water-solubility and self-assembly capabilities, which result in the formation of robust nanoparticles in aqueous solutions with a 50 nm average size.
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