%0 Journal Article
%A Cortijo Montes, Miguel
%A González Prieto, Rodrigo
%A Herrero Domínguez, Santiago
%A Jiménez Aparicio, Reyes
%A Sánchez-Rivera, Paula
%T Ferromagnetic Interactions through Hydrogen Bonds in a One‐Dimensional Ni<sup>II</sup> Coordination Polymer
%D 2013
%@ 1434-1948
%@ 1099-0682
%U https://hdl.handle.net/20.500.14352/93090
%X A one-dimensional coordination polymer [Ni(tp)(OH2)4] (1) (tp = –O2CC6H4CO2–; terephthalate) has been synthesized under environmentally friendly conditions. It has been characterized by elemental analysis, infrared spectroscopy, thermogravimetry, single-crystal and powder X-ray diffraction, and magnetic measurements. Compound 1 is a rare example of 1D polymeric NiII dicarboxylate that shows ferromagnetic interactions through hydrogen bonds. The zigzag arrangement of the NiII octahedral units connected by hydrogen bonds distinguishes compound 1 from other [Ni(dicarboxylate)(OH2)4] compounds, in which the interactions are antiferromagnetic.
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