%0 Journal Article %A Martín-Mejías, Irene %A Aragoncillo Abanades, Cristina %A Yanai, Hikaru %A Hoshikawa, Shoki %A Fujimoto, Yuuki %A Matsumoto, Takashi %A Almendros Requena, Pedro %T A catalyst-free bis(triflyl)ethylation/benzannulation reaction: rapid access to carbazole-based superacidic carbon acids from alkynols %D 2020 %@ 1359-7345 %U https://hdl.handle.net/20.500.14352/91838 %X Carbazoles possessing Tf2CHCH2 groups were obtained by the reaction of 1-(indol-2-yl)but-3-yn-1-ols with in situ-generated Tf2CQCH2 through vicinal difunctionalisation of the alkyne moiety, where the vinyl-type carbocation intermediate was selectively attacked by the indole moiety and not by the carbanion moiety %~