RT Journal Article
T1 A catalyst-free bis(triflyl)ethylation/benzannulation reaction: rapid access to carbazole-based superacidic carbon acids from alkynols
A1 Martín-Mejías, Irene
A1 Aragoncillo Abanades, Cristina
A1 Yanai, Hikaru
A1 Hoshikawa, Shoki
A1 Fujimoto, Yuuki
A1 Matsumoto, Takashi
A1 Almendros Requena, Pedro
AB Carbazoles possessing Tf2CHCH2 groups were obtained by the reaction of 1-(indol-2-yl)but-3-yn-1-ols with in situ-generated Tf2CQCH2 through vicinal difunctionalisation of the alkyne moiety, where the vinyl-type carbocation intermediate was selectively attacked by the indole moiety and not by the carbanion moiety
PB The Royal Society of Chemistry
SN 1359-7345
YR 2020
FD 2020
LK https://hdl.handle.net/20.500.14352/91838
UL https://hdl.handle.net/20.500.14352/91838
LA eng
NO Martín-Mejías I, Aragoncillo C, Yanai H, Hoshikawa S, Fujimoto Y, Matsumoto T, Almendros, P. A Catalyst-Free Bis(triflyl)ethylation/Benzannulation Reaction: Rapid Access to Carbazole-Based Superacidic Carbon Acids from Alkynols. Chem Commun 2020, 56, 1795-1798.
NO Ministerio de Ciencia e Innovación (España)
NO Ministerio de Economía, Comercio y Empresa (España)
NO European Commission
DS Docta Complutense
RD 6 oct 2024