RT Journal Article
T1 N‐Annulated Perylene Bisimides to Bias the Differentiation of Metastable Supramolecular Assemblies into J‐ and H‐Aggregates
A1 Greciano Raiskila, Elisa Emilia
A1 Calbo, Joaquín
A1 Ortí, Enrique
A1 Sánchez Martín, Luis
AB AbstractThe unique self‐assembling features of N‐annulated perylene bisimides (PBIs) 1 and 2 are reported. The stability of the aggregates of diester 1, in which no H‐bonding interactions are operative, corroborates the significance of long‐range van der Waals and dipole–dipole electrostatic interactions in the construction of stable supramolecular assemblies. The incorporation of amide functional groups within the N‐annulated PBI in 2stimulates pathway differentiation to achieve up to three J‐type aggregates and a fourth H‐type aggregate depending on the experimental conditions. The results presented demonstrate unprecedented levels of control over synthetic supramolecular self‐assembly and the rich differentiation that N‐annulated PBIs exhibit, opening the door to new, complex, functional supramolecular materials.
PB John Wiley & Sons, Ltd
SN 1433-7851
YR 2020
FD 2020
LK https://hdl.handle.net/20.500.14352/93158
UL https://hdl.handle.net/20.500.14352/93158
LA eng
NO Greciano, E. E.; Calbo, J.; Ortí, E.; Sánchez, L. N-Annulated Perylene Bisimides to Bias the Differentiation of Metastable Supramolecular Assemblies into J- and H-Aggregates. Angew. Chem. Int. Ed. 2020, 59, 17517-17524 DOI:10.1002/anie.202005837.
NO Ministerio de Ciencia e Innovación (España)
NO Generalitat Valenciana
NO Universidad Complutense de Madrid
NO European Commission
NO Comunidad de Madrid
DS Docta Complutense
RD 24 abr 2025