RT Journal Article T1 Effect of an ac perturbation on the electroosmotic behavior of a cation-exchange membrane. Influence of the cation nature A1 Barragán García, Vicenta María A1 Ruiz Bauzá, Carlos AB The effect of an ac sinusoidal perturbation of known amplitude and frequency superimposed on the usual dc applied electric voltage difference on the electroosmotic flow through a typical cation-exchange membrane has been studied using different monovalent electrolytes. As a general trend, the presence of the ac perturbation increases the value of the electroosmotic flow with respect to the value in the absence of ac perturbation. A dispersion of the electroosmotic permeability on the frequency of the applied ac signal has been found for the three studied electrolytes, observing that the electroosmotic permeability reaches maximum values for some characteristic values of the frequency. This behavior may be related to the different relaxation processes in heterogeneous mediums. PB Academic Press Inc Elsevier Science SN 0021-9797 YR 2001 FD 2001-08-01 LK https://hdl.handle.net/20.500.14352/58424 UL https://hdl.handle.net/20.500.14352/58424 LA eng NO 1. Prigogine, I., “Introduction to Thermodynamics of Irreversible Processes,” 3rd ed. Wiley, New York, 1968.2. De Groot, S. R., “Thermodynamics of Irreversible Processes,” 4th ed. North Holland, Amsterdam, 1966.3. Khedr, G., Schmitt, A., and Varoqui, R., J. Colloid Interface Sci. 66, 516 (1978).4. Demish, H. U., and Pusch, W., J. Colloid Interface Sci. 76, 464 (1980).5. Narebska, A., Kujawski, W., and Kotter, S., J. Membr. Sci. 30, 125 (1987).6. Arulanandam, S., and Dongqing, L., J. Colloid Interface Sci. 225, 421 (2000).7. Martinsen, Ø. G., Grimnes, S., and Karlsen, J., J. Colloid Interface Sci. 199, 107 (1998).8. Plesner, I. W., Malmgren-Hansen, B., and Sørensen, T. S., J. Chem. Soc. Faraday Trans. 90, 2381 (1994).9. Malmgren-Hansen, B., Sørensen, T. S., Jensen, J. B., and Hennenberg, M., J. Colloid Interface. Sci. 130, 359 (1989).10. Holdik, H., Alcaraz, A., Ramírez, P., and Mafé, S., J. Electroanal. Chem. 442, 13 (1998).11. Sørensen, T. S., in “Surface Chemistry and Electrochemistry of Membranes” (T. S. Sørensen, Ed.), Chap. 19. Dekker, New York, 1999.12. Alcaraz, A., Holdik, H., Rufling, T., Ramírez, P., and Mafé, S., J. Membr. Sci. 150, 43 (1998).13. Kuang, W., and Nelson, S. O., J. Colloid Interface Sci. 193, 242 (1997).14. Barragán, V. M., and Ruíz-Bauzá, C., J. Colloid Interface Sci. 230, 359 (2000).15. Ruiz-Bauzá, C., and Rueda-Sánchez, C., J. Non-Equilibr. Thermodyn. 15, 281 (1990).16. Barragán, V. M., Ruiz-Bauzá, C., and Mengual, J. I., J. Membr. Sci. 95, 1 (1994).17. Janz, G. J., in “Reference Electrodes,” Chap. 4. Academic Press, London, 1961.18. Barragán, V. M., and Ruiz-Bauzá, C., J. Colloid Interface Sci. 205, 365 (1998).19. Lakshminarayanaiah, N., J. Electrochem. Soc. 116, 338 (1969).20. McCrum, N. G., Read, B. E., and Williams,G., "Anelastic and Dielectric Effects in Polymeric Solids." Dover, New York, 1991.21. Coster H. G. L., and Chilcott, T. C., in “Surface Chemistry and Electrochemistry of Membranes” (T. S. Sørensen, Ed.), Chap. 19. Dekker, New York, 1999.22. Zholkovskij, E. K., in “Surface Chemistry and Electrochemistry of Membranes” (T. S. Sørensen, Ed.), Chap. 20. Dekker, New York, 1999.23. Helfferich, F., “Ion-Exchange.” McGraw-Hill, New York, 1962.24. Lobo, V. M. M., “Electrolyte Solutions: Literature Data on Thermodynamics and Transport Properties.” Coimbra Editora, Coimbra, Portugal, 1975.25. Lakshminarayanaiah, N., “Transport Phenomena in Membranes.” Academic Press, New York, 1969.26. Bagotzky, V. S., “Fundamentals of Electrochemistry.” Plenum, New York, 1993.27. Bockris, J., and Reddy, A., “Modern Electrochemistry,” Vol. 1. Plenum/ Rosseta, New York, 1973.28. González-Caballero, F., and De las Nieves, F. J., J. Membr. Sci. 16, 225 (1983).29. Barragán, V. M., and Ruiz-Bauzá, C., J. Non-Equilibr. Thermodyn. 22, 374 (1997). NO © 2001 by Academic Press. Financial support from the University Complutense of Madrid under ProjectPR49/98-7756 is gratefully acknowledged. NO Universidad Complutense de Madrid DS Docta Complutense RD 30 abr 2024