RT Journal Article
T1 High-Boron-Content Porphyrin-Cored Aryl Ether Dendrimers: Controlled Synthesis, Characterization, and Photophysical Properties
A1 Cabrera González, Justo Enrique
A1 Xochitiotzi-Flores, Elba
A1 Viñas, Clara
A1 Teixidor, Francesc
A1 García-Ortega, Héctor
A1 Farfán, Noberto
A1 Santillan, Rosa
A1 Parella, Teodor
A1 Núñez, Rosario
AB The synthesis and characterization of a set of poly(aryl ether) dendrimers with tetraphenylporphyrin as the core and 4, 8, 16, or 32 closo-carborane clusters are described. A regioselective hydrosilylation reaction on the allyl-terminated functions with carboranylsilanes in the presence of Karstedt's catalyst leads to different generations of boron-enriched dendrimers. This versatile approach allows the incorporation of a large number of boron atoms in the dendrimers' periphery. Translational diffusion coefficients (D) determined by DOSY NMR experiments permit estimation of the hydrodynamic radius (RH) and molecular size for each dendrimer. Furthermore, a notable correlation between D and the molecular weight (MW) is found and can be used to predict their overall size and folding properties. The UV vis and emission behavior are not largely affected by the functionalization, therefore implying that the presence of carboranes does not alter their photoluminescence properties.
PB American Chemical Society
YR 2015
FD 2015
LK https://hdl.handle.net/20.500.14352/96340
UL https://hdl.handle.net/20.500.14352/96340
LA eng
NO Cabrera-González, Justo, et al. «High-Boron-Content Porphyrin-Cored Aryl Ether Dendrimers: Controlled Synthesis, Characterization, and Photophysical Properties». Inorganic Chemistry, vol. 54, n.o 10, mayo de 2015, pp. 5021-31. DOI.org (Crossref), https://doi.org/10.1021/acs.inorgchem.5b00618.
DS Docta Complutense
RD 5 abr 2025